
Leadum DBScribe is a free powerful tool to document your MySQL database into HTML, CHM help, MS Word Documentation.
It supports:

rich set of output formats and styles

wizard and command line interfaces

complete database structure documenting

all SQL object types, their details and properties

custom documentation profile

DBScribe helps you to:

Dramatically reduce time and cost necessary to document your databases

Avoid document updating and synchronization after database changes

Manage your product/solution knowledgebase

Optimize communication between your IT team members: database administrators, developers, testers and technical writers

Increase your customer satisfaction by providing comprehensive, professional looking database documentation